资源类型

期刊论文 70

年份

2023 6

2022 6

2021 2

2020 3

2019 2

2018 5

2017 3

2016 2

2015 4

2014 4

2013 2

2012 4

2011 1

2010 6

2009 5

2008 4

2007 3

2006 2

2005 2

2003 2

展开 ︾

关键词

碳酸盐岩 3

机理 2

CP）；符号间干扰（inter symbol interference， ISI）；载波间干扰（inter carrier interference 1

Chrestenson谱 1

ICI）；最大似然估计（maximum likelihood estimation 1

MLE） 1

OFDM）；快速傅立叶变换（Fast Fourier transform， FFT）；循环前缀（cyclic prefix 1

m值逻辑函数 1

pH值 1

严格雪崩准则 1

假单胞菌 1

储层预测 1

动力学 1

参数优选 1

含气性预测 1

周期平稳 1

周期注水 1

周期采油 1

地下水 1

展开 ︾

检索范围：

排序： 展示方式：

Recent advances in cycloaddition of CO with epoxides: halogen-free catalysis and mechanistic insights

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 1879-1894 doi: 10.1007/s11705-023-2354-4

摘要： The atom-economical cycloaddition of CO2 with epoxides to synthesize cyclic carbonates is a promising route for valuable utilization of CO2. Halogenide such as alkali metal halides and quaternary ammonium salt have been developed as the efficient catalysts. However, the spilled halogen causes equipment corrosion and affects the product purity. To address these concerns, the halogen-free cycloaddition of CO2 with epoxides has always been desired. In this review, we systematically discussed the halogen-free catalysis for cycloaddition of CO2 with epoxides from the mechanistic insights, aiming to promote the development of efficient halogen-free catalysts. Two types of catalysts, i.e., alternatives of halogen nucleophiles for epoxide activation, and bifunctional catalysts with Lewis acid-base sites for synergistic activation of CO2 and epoxides are summarized and emphasized. Specially, metal oxides as the potential halogen-free catalysts are highlighted due to their flexible acid-base sites for synergistic activation of CO2 and epoxides, facile preparation, and low cost.

关键词： carbon dioxide     halogen-free catalysis     cyclic carbonate     mechanistic insight    

HTML PDF 收藏

Cationic organobismuth complex as an effective catalyst for conversion of CO

Xiaowen ZHANG, Weili DAI, Shuangfeng YIN, Shenglian LUO, Chak-Tong AU

《环境科学与工程前沿（英文）》 2009年 第3卷 第1期   页码 32-37 doi: 10.1007/s11783-008-0068-y

摘要： In order to achieve high-efficiency conversion of CO into valuable chemicals, and to exploit new applications of organobismuth compounds, cationic organobismuth complex with 5,6,7,12-tetrahydrodibenz[c,f] azabismocine framework was examined for the first time for the coupling of CO into cyclic carbonates, using terminal epoxides as substrates and tetrabutylammonium halide as co-catalyst in a solvent-free environment under mild conditions. It is shown that the catalyst exhibited high activity and selectivity for the coupling reaction of CO with a wide range of terminal epoxide. The selectivity of propylene carbonates could reach 100%, and the maximum turnover frequency was up to 10740 h at 120°C and 3 MPa CO pressure when tetrabutylammonium iodide was used as co-catalyst. Moreover, the catalyst is environment friendly, resistant to air and water, and can be readily reused and recycled without any loss of activity, demonstrating a potential in industrial application.

关键词： cationic organobismuth complex     terminal epoxide     carbon dioxide     coupling     cyclic carbonate    

HTML PDF 收藏

Polyethylene glycol-supported ionic liquid as a highly efficient catalyst for the synthesis of propylene carbonate

Rui YAO, Hua WANG, Jinyu HAN

《化学科学与工程前沿（英文）》 2012年 第6卷 第3期   页码 239-245 doi: 10.1007/s11705-012-1297-y

摘要： The coupling reaction of propylene and CO to form propylene carbonate (PC) was promoted by an ionic liquid (IL) covalently bound to polyethylene glycol (PEG). The supported ionic liquid, which has both acidic and basic components, proved to be an active catalyst for PC synthesis under mild conditions. The effects of different cations and anions, reaction temperature, CO pressure, and reaction time were investigated. It was demonstrated that the acid group in the catalyst plays an important role in the reaction. With this system, a high PC yield (95%) was achieved under mild conditions (3.0 MPa, 120°C and 4 h) without a co-solvent. In addition, the catalyst was readily recovered and reused. Based on the experimental results, a plausible mechanism for the catalyst was proposed.

关键词： ionic liquid     PEG-supported ionic liquid     carbon dioxide     propylene carbonate    

HTML PDF 收藏

Effect of wastewater composition on the calcium carbonate precipitation in upflow anaerobic sludge blanket

Shucheng YANG, Yanling HE, Charles CHOU, Pengxiang ZHANG, Dongqi WANG, Yonghong LIU,

《环境科学与工程前沿（英文）》 2010年 第4卷 第2期   页码 142-149 doi: 10.1007/s11783-010-0026-3

摘要： Calcium carbonate often precipitates in anaerobic reactors treating wastewater with high calcium content. The aim of this paper is to study the effect of wastewater composition on calcium carbonate precipitation in upflow anaerobic sludge blanket (UASB) reactors. Two laboratory-scale UASB reactors were operated with calcium-containing influents using acetate and carbohydrate as substrate, respectively. There was an obvious accumulation of inorganic precipitate observed in the biogranules. Observations via scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS) showed that the acclimated biogranules in the two reactors differed in microstructure. Calcium carbonate was found to have precipitated on the surface of acetate-degrading biogranules, but precipitated at the core of the carbohydrate-degrading biogranules. The results indicated that substrates had significant influence on the location of calcium carbonate precipitation in anaerobic granular sludge, which was expected due to the different methanogens distribution and pH gradient within the granular sludge degrading various substrates. Moreover, the location of calcium carbonate precipitation substantially affected the specific methanogenic activity (SMA) of the granular sludge. The SMA of the acetate-degrading biogranules dropped from 1.96 gCOD·gVSS·d to 0.61 gCOD·gVSS·d after 180-d of operation in the reactor. However, the SMA of the carbohydrate-degrading biogranules was not adversely affected by calcium carbonate precipitation.

关键词： calcium carbonate     precipitation     anaerobic granular sludge     wastewater composition     microstructure     upflow anaerobic sludge blanket (UASB)    

HTML PDF 收藏

Novel eco-efficient reactive distillation process for dimethyl carbonate production by indirect alcoholysis

Iulian Patraşcu, Costin S. Bîldea, Anton A. Kiss

《化学科学与工程前沿（英文）》 2022年 第16卷 第2期   页码 316-331 doi: 10.1007/s11705-021-2047-9

摘要： Dimethyl carbonate is an eco-friendly essential chemical that can be sustainably produced from CO , which is available from carbon capture activities or can even be captured from the air. The rapid increase in dimethyl carbonate demand is driven by the fast growth of polycarbonates, solvent, pharmaceutical, and lithium-ion battery industries. Dimethyl carbonate can be produced from CO through various chemical pathways, but the most convenient route reported is the indirect alcoholysis of urea. Previous research used techniques such as heat integration and reactive distillation to reduce the energy use and costs, but the use of an excess of methanol in the trans-esterification step led to an energy intensive extractive distillation required to break the dimethyl carbonate-methanol azeotrope. This work shows that the production of dimethyl carbonate by indirect alcoholysis of urea can be improved by using an excess of propylene carbonate (instead of an excess of methanol), a neat feat that we showed it requires only 2.64 kW·h·kg dimethyl carbonate in a reaction-separation-recycle process, and a reactive distillation column that effectively replaces two conventional distillation columns and the reactor for dimethyl carbonate synthesis. Therefore, less equipment is required, the methanol-dimethyl carbonate azeotrope does not need to be recycled, and the overall savings are higher. Moreover, we propose the use of a reactive distillation column in a heat integrated process to obtain high purity dimethyl carbonate (>99.8 wt-%). The energy requirement is reduced by heat integration to just 1.25 kW·h·kg dimethyl carbonate, which is about 52% lower than the reaction-separation-recycle process. To benefit from the energy savings, the dynamics and control of the process are provided for ±10% changes in the nominal rate of 32 ktpy dimethyl carbonate, and for uncertainties in reaction kinetics.

关键词： dimethyl carbonate     reactive distillation     process design     plantwide control    

HTML PDF 收藏

地下水碳酸平衡检查系统

刘建刚,郑克勋,傅伟宁,吴顺华

《中国工程科学》 2003年 第5卷 第9期   页码 61-64

摘要：

文章主要研究地下水在不同温度和CO2分压条件下碳酸三种存在形式与pH值的关系，以便更有效地对地下水水质资料进行可靠性检查。分析认为HCO3-出现峰值的分界pH0值，纯水在CO2分压1～105Pa，温度0～30℃时的变化范围为7.92～8.60，碳酸盐岩地下水的变化范围为8.28～8.57。pH0值随温度的升高而降低。石灰岩和白云岩的pH0十分接近，碳酸盐岩地区的平衡特性将取决于方解石成分。

关键词： 碳酸盐岩     地下水     碳酸平衡     pH值    

HTML PDF 收藏

Multi-objective optimization of molten carbonate fuel cell system for reducing CO

Ramin ROSHANDEL,Majid ASTANEH,Farzin GOLZAR

《能源前沿（英文）》 2015年 第9卷 第1期   页码 106-114 doi: 10.1007/s11708-014-0341-7

摘要： The aim of this paper is to investigate the implementation of a molten carbonate fuel cell (MCFC) as a CO separator. By applying multi-objective optimization (MOO) using the genetic algorithm, the optimal values of operating load and the corresponding values of objective functions are obtained. Objective functions are minimization of the cost of electricity (COE) and minimization of CO emission rate. CO tax that is accounted as the pollution-related cost, transforming the environmental objective to the cost function. The results show that the MCFC stack which is fed by the syngas and gas turbine exhaust, not only reduces CO emission rate, but also produces electricity and reduces environmental cost of the system.

关键词： molten carbonate fuel cell (MCFC)     multi-objective optimization (MOO)     Pareto curve     genetic algorithm     CO2 separation    

HTML PDF 收藏

An enhanced damage plasticity model for predicting the cyclic behavior of plain concrete under multiaxial

Mohammad Reza AZADI KAKAVAND, Ertugrul TACIROGLU

《结构与土木工程前沿（英文）》 2020年 第14卷 第6期   页码 1531-1544 doi: 10.1007/s11709-020-0675-7

摘要： Some of the current concrete damage plasticity models in the literature employ a single damage variable for both the tension and compression regimes, while a few more advanced models employ two damage variables. Models with a single variable have an inherent difficulty in accounting for the damage accrued due to tensile and compressive actions in appropriately different manners, and their mutual dependencies. In the current models that adopt two damage variables, the independence of these damage variables during cyclic loading results in the failure to capture the effects of tensile damage on the compressive behavior of concrete and vice-versa. This study presents a cyclic model established by extending an existing monotonic constitutive model. The model describes the cyclic behavior of concrete under multiaxial loading conditions and considers the influence of tensile/compressive damage on the compressive/tensile response. The proposed model, dubbed the enhanced concrete damage plasticity model (ECDPM), is an extension of an existing model that combines the theories of classical plasticity and continuum damage mechanics. Unlike most prior studies on models in the same category, the performance of the proposed ECDPM is evaluated using experimental data on concrete specimens at the material level obtained under cyclic multiaxial loading conditions including uniaxial tension and confined compression. The performance of the model is observed to be satisfactory. Furthermore, the superiority of ECDPM over three previously proposed constitutive models is demonstrated through comparisons with the results of a uniaxial tension-compression test and a virtual test.

关键词： damage plasticity model     plain concrete     cyclic loading     multiaxial loading conditions    

HTML PDF 收藏

Isogeometric analysis of coupled thermo-elastodynamic problems under cyclic thermal shock

Asghar AMANI DASHLEJEH

《结构与土木工程前沿（英文）》 2019年 第13卷 第2期   页码 397-405 doi: 10.1007/s11709-018-0473-7

摘要： The isogeometric analysis (IGA) method was extended for the solution of the coupled thermo-elastodynamic equations. The dimensionless formulation was accepted in discretization of the uncoupled and coupled thermoelasticity equations and the Generalized Newmark method was used in the time integration procedure. First, the performance of the proposed method was verified against a two-dimensional benchmark example subjected to constant thermal shock with available exact analytical solutions. Then a two-dimensional half-space benchmark example under thermal shock was solved. Finally, cyclic thermal shock (CTS) loading was applied on the half-space problem. The results dedicated that IGA can be used as a suitable approach in the analysis of the general thermomechanical problems.

关键词： isogeometric analysis     coupled thermo-elastodynamic     dynamic analysis     generalized newmark     cyclic thermal shock    

HTML PDF 收藏

Effect of potassium carbonate on catalytic synthesis of calcium carbide at moderate temperature

Dejun SHI, Ke QIAO, Zifeng YAN

《化学科学与工程前沿（英文）》 2011年 第5卷 第3期   页码 372-375 doi: 10.1007/s11705-010-0570-1

摘要： Calcium carbide was successfully synthesized by carbothermal reduction of lime with coke at 1973 K for 1.5 h. The effect of potassium carbonate as additive on the composition and morphology of the product was investigated using X-ray diffraction and scanning electron microscope. Addition of potassium carbonate increased the yield of calcium carbide. The sample in the presence of potassium carbonate generated acetylene gas of 168.3 L/kg, which was 10% higher than that in the absence of potassium carbonate. This result confirmed the catalytic effect of potassium carbonate on the synthesis of calcium carbide. A possible mechanism of the above effects was that the additive, which was melted at the reduction temperature, dissolved CaO and so promoted the contact between CaO and carbon, which was essential for the solid-solid reaction to form calcium carbide.

关键词： calcium carbide     synthesis     catalysis    

HTML PDF 收藏

Prediction of cyclic large plasticity for prestrained structural steel using only tensile coupon tests

Liang-Jiu JIA, Tsuyoshi KOYAMA, Hitoshi KUWAMURA

《结构与土木工程前沿（英文）》 2013年 第7卷 第4期   页码 466-476 doi: 10.1007/s11709-013-0219-5

摘要： Cold-formed steel members, which experience complicated prestrain histories, are frequently applied in structural engineering. This paper aims to predict cyclic plasticity of structural steels with tensile and compressive prestrain. Monotonic and cyclic tests on hourglass specimens with tensile and compressive prestrain are conducted, and compared with numerical simulations using the Chaboche model. Two approaches are taken in the simulation. The first requires only the monotonic tensile test data from the prestrained steels, and the second requires both the monotonic tensile test data from the virgin steel and the prestrain histories. The first approach slightly overestimates the compressive stress for specimens with tensile prestrain, while the second approach is able to accurately predict the cyclic plasticity in specimens with tensile and compressive prestrain.

关键词： cyclic plasticity     prestrain     Chaboche model     mild steel    

HTML PDF 收藏

Influence of crystalline phase of Li-Al-O oxides on the activity of Wacker-type catalysts in dimethyl carbonate

Yadong GE, Yuanyuan DONG, Shengping WANG, Yujun ZHAO, Jing LV, Xinbin MA

《化学科学与工程前沿（英文）》 2012年 第6卷 第4期   页码 415-422 doi: 10.1007/s11705-012-1214-4

摘要： The catalysts supported on LiAl O (spinel) for vapor phase synthesis of dimethyl carbonate (DMC) from methyl nitrite (MN) have been studied. Their catalytic activities on supports prepared by different methods were evaluated in a continuous reactor. The samples were characterized by powder X-ray diffraction, N adsorption-desorption isotherms, fourier transform infrared spectroscopy and temperature-programmed reduction of H . Li/Al molar ratio and calcination temperature greatly influence the structure of crystalline phase of Li-Al-O oxides. Desirable LiAl O (spinel) was formed at 800°C, while LiAl O (primitive cube) formed at 900°C is undesirable for the reaction. A high Li/Al molar ratio, which was related with LiAlO , also slowed the reaction rate. The electron transfer ability and the interaction with active component are the important properties of the spinel-based supports. The CuCl -PdCl /LiAl O (spinel) with better electron transfer ability and low Pd reduction temperature exhibited a better catalytic ability.

关键词： Wacker-type catalyst     dimethyl carbonate     methyl nitrite     spinel    

HTML PDF 收藏

Direct synthesis of diphenyl carbonate over heterogeneous catalyst: effects of structure of substituted

WU Guangwen, JIN Fang, WU Yuxin, ZHANG Guangxu, LI Dinghuo, WANG Cunwen, MA Peisheng

《化学科学与工程前沿（英文）》 2007年 第1卷 第1期   页码 59-64 doi: 10.1007/s11705-007-0012-x

摘要： The perovskite-type compound LaMnO was substituted for the part of La in position A and for the part of Mn in position B by citrate method. The phases were detected by X-ray diffraction. Powder morphologies were scanned by scanning electron microscopy. The valence of atoms was determined by X-ray photoelectron spectroscopy. It was found that the perovskite can form crystal defect and increase the proportion of high valence B element by doping. Active component Pd was loaded on various perovskite supports for synthesis of diphenyl carbonate. The results showed that the activities of catalysts in which supports have crystal defect by substitution were higher. It can be concluded that perovskite with defect structure by doping could lead to the formation of oxygen vacancy where the lattice oxygen became exchangeable with the oxygen gas. Also, this improved the redox process of the carrier by transferring electrons and activities of catalysts.

关键词： photoelectron spectroscopy     diphenyl carbonate     proportion     diffraction     perovskite    

HTML PDF 收藏

循环双谱及在周期平稳类故障中的应用

苏中元,贾民平,许飞云,胡建中

《中国工程科学》 2006年 第8卷 第9期   页码 57-60

摘要：

论述了未知循环频率的周期平稳信号循环双谱的估计方法；研究了在循环双谱的循环累积量计算中涉及变量的简化存储方法，提出了该变量矩阵是对称阵，通过算法可以三角阵的元素来表述，克服了循环双谱传统估计方法计算量较大的缺陷，提高了运算效率；提出了循环双谱对调相故障信号的分析能力，以及对加性噪声的处理能力，仿真并验证了该方法的有效性，并将其应用于旋转机械状态分析。

关键词： 周期平稳     循环双谱     滞后积    

HTML PDF 收藏

Experimental research on seismic behavior of recycled concrete frame under varying cyclic loading

SUN Yuedong, XIAO Jianzhuang, ZHOU Deyuan

《结构与土木工程前沿（英文）》 2008年 第2卷 第4期   页码 302-308 doi: 10.1007/s11709-008-0050-6

摘要： A study is conducted on the seismic behavior of one natural concrete frame and two recycled concrete frames with 100% recycled coarse aggregate whose scales are 1:2 entirely, and a comparative study is conducted under low-reversed cyclic lateral loading and different vertical loading. This work aims to estimate the failure mechanism, hysteresis loops, displacement ductility, deterioration of strength and stiffness and energy dissipation of recycled concrete frames under low-reversed cyclic loading as well as the influence of different vertical loading. Analysis on the basis of the experiment proves that it is entirely feasible to apply recycled concrete to practical engineering for the sake of its good seismic behaviors. Theoretical base is provided for further study and practical application of recycled concrete structure.

关键词： different     aggregate     stiffness     practical application     % recycled    

HTML PDF 收藏

标题 作者 时间 类型 操作

Recent advances in cycloaddition of CO with epoxides: halogen-free catalysis and mechanistic insights

期刊论文

Cationic organobismuth complex as an effective catalyst for conversion of CO

Xiaowen ZHANG, Weili DAI, Shuangfeng YIN, Shenglian LUO, Chak-Tong AU

期刊论文

Polyethylene glycol-supported ionic liquid as a highly efficient catalyst for the synthesis of propylene carbonate

Rui YAO, Hua WANG, Jinyu HAN

期刊论文

Effect of wastewater composition on the calcium carbonate precipitation in upflow anaerobic sludge blanket

Shucheng YANG, Yanling HE, Charles CHOU, Pengxiang ZHANG, Dongqi WANG, Yonghong LIU,

期刊论文

Novel eco-efficient reactive distillation process for dimethyl carbonate production by indirect alcoholysis

Iulian Patraşcu, Costin S. Bîldea, Anton A. Kiss

期刊论文

地下水碳酸平衡检查系统

刘建刚,郑克勋,傅伟宁,吴顺华

期刊论文

Multi-objective optimization of molten carbonate fuel cell system for reducing CO

Ramin ROSHANDEL,Majid ASTANEH,Farzin GOLZAR

期刊论文

An enhanced damage plasticity model for predicting the cyclic behavior of plain concrete under multiaxial

Mohammad Reza AZADI KAKAVAND, Ertugrul TACIROGLU

期刊论文

Isogeometric analysis of coupled thermo-elastodynamic problems under cyclic thermal shock

Asghar AMANI DASHLEJEH

期刊论文

Effect of potassium carbonate on catalytic synthesis of calcium carbide at moderate temperature

Dejun SHI, Ke QIAO, Zifeng YAN

期刊论文

Prediction of cyclic large plasticity for prestrained structural steel using only tensile coupon tests

Liang-Jiu JIA, Tsuyoshi KOYAMA, Hitoshi KUWAMURA

期刊论文

Influence of crystalline phase of Li-Al-O oxides on the activity of Wacker-type catalysts in dimethyl carbonate

Yadong GE, Yuanyuan DONG, Shengping WANG, Yujun ZHAO, Jing LV, Xinbin MA

期刊论文

Direct synthesis of diphenyl carbonate over heterogeneous catalyst: effects of structure of substituted

WU Guangwen, JIN Fang, WU Yuxin, ZHANG Guangxu, LI Dinghuo, WANG Cunwen, MA Peisheng

期刊论文

循环双谱及在周期平稳类故障中的应用

苏中元,贾民平,许飞云,胡建中

期刊论文

Experimental research on seismic behavior of recycled concrete frame under varying cyclic loading

SUN Yuedong, XIAO Jianzhuang, ZHOU Deyuan

期刊论文